Crystallographic group

Crystallographic restriction theorem

The crystallographic restriction theorem is a group theoretic and geometric result which places an important restriction on which point groups can form crystallographic groups.

Let 𝑆 be a crystallographic group on a lattice 𝐿 of 2 or 3 with point group 𝑆/𝐿. Then the order of elements in 𝑆/𝐿 are in {1,2,3,4,6} #m/thm/group

Trigonometric proof

Consider two lattice points 𝐴,𝐵 with separation vector 𝐴𝐵, and suppose that rotation by an angle 𝛼 is a symmetry operation. Then 𝐵 =𝐴 +𝑅𝛼𝐴𝐵 and 𝐴 =𝐵 +𝑅𝛼𝐵𝐴 are also lattice points. It follows that 𝐴𝐵 =𝑚𝐴𝐵 for some 𝑚 . The vectors 𝐴𝐵,𝑅𝛼𝐴𝐵,𝑅𝛼𝐵𝐴,𝐴𝐵 form a trapezium, therefore the length of 𝐴𝐵 is given by

|𝐴𝐵|=|𝐴𝐵|(2cos𝛼1)

thus letting 𝑀 =𝑚 +1

cos𝛼=𝑀2

whence follows 𝑀 { 2, 1,0,1,2}, thus 𝛼 =2𝜋𝑛 for 𝑛 {1,2,3,4,6}.

Generalized theorem

See @bambergCrystallographicRestrictionPermutations2003


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