Wavefunction

Wavefunction in position space

For a system in which position is the only degree of freedom, we may choose eigenfunctions of the position operator Λ†π‘₯ as a basis. Thus Ξ¨ :ℝ3 ×ℝ β†’β„‚ is a wavefunction in position space. The Hamiltonian operator may then be represented as

ˆ𝐻(𝑑)=ˆ𝐩⋅ˆ𝐩2π‘š+𝑉(ˆ𝐱,𝑑)=βˆ’β„22π‘šβˆ‡2+𝑉(ˆ𝐱,𝑑)

wherefore the SchrΓΆdinger equation becomes

π‘–β„πœ•πœ•π‘‘Ξ¨(⃗𝐱,𝑑)=βˆ’β„2π‘šβˆ‡2Ξ¨(⃗𝐱,𝑑)+𝑉(⃗𝐱,𝑑)Ξ¨(⃗𝐱,𝑑)

See also


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